The structures and stereochemistry of majdine and isomaydine.

نویسندگان

  • I Ognyanov
  • B Pyuskyulev
  • I Kompis
  • T Sticzay
  • G Spiteller
  • M Shamma
  • R J Shine
چکیده

On direct comparison by TLC and IR we established that the alkaloids A-5 and A-4, first isolated from Vinca herbacea W. K . 1 are identical to the oxindole alkaloid majdine (I), later isolated from Vinca major L. 2' 3 and with its isomer isomajdine (II), prepared by heating of (I) in acetic anhydride 2. Based upon some spectroscopic evidence it was claimed2, that majdine was a diastereomer of carapanaubine (III) 4, while isomajdine differed by the configuration at C-3.

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عنوان ژورنال:
  • Zeitschrift fur Naturforschung. Teil B, Chemie, Biochemie, Biophysik, Biologie und verwandte Gebiete

دوره 23 2  شماره 

صفحات  -

تاریخ انتشار 1968